Preparation of cerium oxide nanoparticles in Salvia Macrosiphon Boiss seeds extract and investigation of their photo-catalytic activities

Autor: Majid Darroudi, Behrouz Elahi, Mohammad Sadegh Amiri, Reza Kazemi Oskuee, Kayvan Sadri, Mahdi Mirzaee
Rok vydání: 2019
Předmět:
Zdroj: Ceramics International. 45:4790-4797
ISSN: 0272-8842
DOI: 10.1016/j.ceramint.2018.11.173
Popis: Cerium oxide nanoparticles (CNPs) with desired particle size and spherical morphology were prepared from cerium nitrate in bio media of Salvia macrosiphon Boiss seeds extract, as a green synthesis route. Then they were characterized by XRD, UV–Vis and FTIR spectroscopies, FESEM and TGA. Band gap energy of the prepared powders was also determined which was found in the range of 2.5–3.5 eV. Determination of DLS and zeta potential were showed that CNPs had the small size and unique colloidal stability, respectively. Then the photo-catalytic activity of them was investigated by degradation of Rhodamine B (RhB) dye as a model of waste water pollutants, under UV-irradiation and optimum conditions were evaluated. Results showed that decreasing the particle size increased the rate of photo-catalytic reaction remarkably but ascending the band gap energy, in contrast. The photo-catalytic mechanism was also studied by using different scavengers.
Databáze: OpenAIRE