Band model for electron emission from diamond-like carbon and diamond

Autor: John Robertson, W. I. Milne
Rok vydání: 1998
Předmět:
Zdroj: Journal of Non-Crystalline Solids. :558-564
ISSN: 0022-3093
DOI: 10.1016/s0022-3093(98)00189-6
Popis: Electron field emission data from diamond-like carbon and diamond is summarised and a band model is proposed to interpret it. The model is constructed from existing data on electron affinities and band offsets, within a theory of band offsets. In diamond, there is a large offset for the conduction band at the back-contact, causing this to be the dominant tunnel barrier for electron emission. Nitrogen and grain boundaries reduce this barrier by forming a depletion layer of ionised donors, which reduces the tunnelling distance. In diamond-like carbon, the conduction band offset at the back-contact is small and the dominant barrier is at the surface. Nitrogen decreases the emission barrier by increasing the bulk Fermi level and decreasing the work function.
Databáze: OpenAIRE