Total synthesis in the steroid series. II: d,l −3-ethylenedioxy-11 β-hydroxy-17-oxymethyl-D-homoandrosta-5: 16-diene 18-acid lactone (18 → 11), an intermediate to aldosterone

Autor:	C. M. Siegmann, W. J. van der Burg, S. A. Szpilfogel, D. A. van Dorp
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Aldosterone Diene Stereochemistry medicine.medical_treatment Total synthesis General Chemistry Steroid chemistry.chemical_compound chemistry medicine Derivative (chemistry) Lactone Ethylenedioxy
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 77:157-170
ISSN:	0165-0513
DOI:	10.1002/recl.19580770208
Popis:	Attempts to transform potential intermediates prepared earlier into 18-oxygenated steroids are described. One of the routes lead to the substiuted D-homoandrostane derivative (XXIX) mentioned in the title.
Databáze:	OpenAIRE
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