Effect of the energy of zero vibrations and the entropy of reagents on the kinetic isotopic effect of the hydrogen evolution reaction

Autor:	L. I. Krishtalik
Rok vydání:	2000
Předmět:	Vibration Hydrogen chemistry Reagent Kinetic isotope effect Electrochemistry chemistry.chemical_element Thermodynamics Hydrogen evolution Kinetic energy Hydronium ion
Zdroj:	Russian Journal of Electrochemistry. 36:799-801
ISSN:	1608-3342 1023-1935
DOI:	10.1007/bf02757685
Popis:	The effect the difference in zero energies and entropies of isotopic forms of reagents has on the difference in free energies of the elementary act of discharge of a hydronium ion for an initial equilibrium configuration of a reaction complex and equilibrium (ground) energy levels is considered. The analysis is performed for conditions of constancy of potential and constancy of overvoltage: only in the latter case one does not have to resort to extrathermodynamic assumptions. It is shown that differences in entropies of isotopic forms play a substantial role
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::94c9efd5435b9e9e5fdc6b201942a4f8 https://doi.org/10.1007/bf02757685 Zobrazit plný text záznamu Full text from SpringerLink