Multicomponent Polyanions. 47. The Aqueous Vanadophosphate System

Autor:	Anna Selling, Lage Pettersson, Shannan L. Downey, Ingegaerd Andersson, Charles M. Schramm, John H. Grate
Rok vydání:	1994
Předmět:	Inorganic Chemistry Speciation Aqueous solution Chemistry Metastability media_common.quotation_subject Inorganic chemistry Vanadium chemistry.chemical_element Physical and Theoretical Chemistry Mass spectrometry media_common
Zdroj:	Inorganic Chemistry. 33:3141-3150
ISSN:	1520-510X 0020-1669
Popis:	Equilibrium and metastable speciations in the aqueous vanadophosphate system in 0.6 M Na(CI) medium at 25 o C have been characterized by pH-potentiometry and high-field 31 P and 51 V NMR spectrometry. Equilibrations are slow at 25 o C, requiring months to years to reach equilibrium. The simultaneous analysis of [H + ]-emf data with 31 P and 51 V NMR shift and integral data was required to establish the speciation in aged, equilibrated solutions. Vanadophosphate speciw exist at equilibrium in solutions at 1.3
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::94bc737a0957be9aa775470b253173e6 https://doi.org/10.1021/ic00092a021 Zobrazit plný text záznamu