Reduction of silica-supported bis-allyl rhodium by H2: characterization by 1H n.m.r. spectroscopy

Autor:	Stephen J. DeCanio, H. C. Foley, Bruce C. Gates, Cecil Dybowski
Rok vydání:	1982
Předmět:	Propene chemistry.chemical_compound Chemistry Propane Polymer chemistry Molecular Medicine Organic chemistry chemistry.chemical_element Spectroscopy Toluene Rhodium
Zdroj:	Journal of the Chemical Society, Chemical Communications. :1372
ISSN:	0022-4936
DOI:	10.1039/c39820001372
Popis:	Surface 1H n.m.r. spectroscopy provided details of the reaction of the SiO2-supported complex SlL–O–Rh(allyl)2 with H2 at 298 K, leading to propane, propene, and highly dispersed supported Rh metel, which was catalytically active for toluene hydrogenation.
Databáze:	OpenAIRE
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