Cu(III)-Mediated Aerobic Oxidations
| Autor: | Kenneth Virgel N. Esguerra, Jean-Philip Lumb |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
biology 010405 organic chemistry Chemistry Methane monooxygenase Organic Chemistry Redox cycle chemistry.chemical_element Context (language use) 010402 general chemistry 01 natural sciences Combinatorial chemistry Redox Copper Catalysis 0104 chemical sciences Adduct Enzyme biology.protein |
| Zdroj: | Synthesis. 51:334-358 |
| ISSN: | 1437-210X 0039-7881 |
| Popis: | CuIII species have been invoked in many copper-catalyzed transformations including cross-coupling reactions and oxidation reactions. In this review, we will discuss seminal discoveries that have advanced our understanding of the CuI/CuIII redox cycle in the context of C–C and C–heteroatom aerobic cross-coupling reactions, as well as C–H oxidation reactions mediated by CuIII–dioxygen adducts.1 General Introduction2 Early Examples of CuIII Complexes3 Aerobic CuIII-Mediated Carbon–Heteroatom Bond-Forming Reactions4 Aerobic CuIII-Mediated Carbon–Carbon Bond-Forming Reactions5 Bioinorganic Studies of CuIII Complexes from CuI and O2 5.1 O2 Activation5.2 Biomimetic CuIII Complexes from CuI and Dioxygen5.2.1 Type-3 Copper Enzymes and Dinuclear Cu Model Complexes5.2.2 Particulate Methane Monooxygenase and Di- and Trinuclear Cu Model Complexes5.2.3 Dopamine–β-Monooxygenase and Mononuclear Cu Model Complexes6 Conclusion |
| Databáze: | OpenAIRE |
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