Resolution of theoptical spectra of sodium solutions in liquid ammonia into two experimentally unresolvable bands

Autor:	Sidney Golden, Gabriel Rubinstein, Thomas R. Tuttle
Rok vydání:	1973
Předmět:	Sodium Resolution (electron density) General Engineering Analytical chemistry chemistry.chemical_element Solvated electron Spectral line Optical spectra Dilution Ammonia chemistry.chemical_compound chemistry Liquid ammonia Physical and Theoretical Chemistry Atomic physics
Zdroj:	The Journal of Physical Chemistry. 77:2872-2877
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100642a010
Popis:	Spectra of the solvated electron were determined at --55, -65, and --75 deg C for solutions in NH/sub 3/ and in NH/sub 3/ 0.08 M in Nal by extrapolations to inflnite dilution. Spectra obtained for Na-NH/sub 3/ solutions and for Na-NH/ sub 3/-Nal solutions were shown to fulflll the expectations of a two absorber model. The data rule out the possibility that the second absorber incorporates only a single solvated electron. The data support the assumption that the second absorber involves a binary combination of solvated electrons. Spectra of the second absorber are obtained at all three temperatures and for solutions in both NH/sub 3/ and in NH/sub 3/ 0.08 M in Nal. Spectra due to Gold and Jolly appear to be characteristic of the second absorber and not the solvated electron. (auth)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::948600fe6a56a3676e92641d3e6459de https://doi.org/10.1021/j100642a010