Synthesis and X-ray diffraction data of 1-[N-(methyl)-(3,5-dimethylphenylamino)]methylnaphthalene
| Autor: | H. A. Camargo, Vladimir V. Kouznetsov, Diego F Amado, José A. Henao, N. M. Habran |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
Aldimine Radiation chemistry.chemical_element Condensed Matter Physics Iodine Chemical formula Medicinal chemistry Potassium carbonate chemistry.chemical_compound Crystallography chemistry X-ray crystallography Acetone General Materials Science Instrumentation Powder diffraction Monoclinic crystal system |
| Zdroj: | Powder Diffraction. 26:74-77 |
| ISSN: | 1945-7413 0885-7156 |
| DOI: | 10.1154/1.3540774 |
| Popis: | The 1-[N-(methyl)-(3,5-dimethylphenylamino)]methylnaphthalene (chemical formula C20H21N) was prepared by means of a condensation between alpha-naphthylaldehyde and 3,5-dimethylaniline in anhydrous ethanol to obtain the aldimine (1) which was reduced with NaBH4 to afford the 1-[N-(3,5-dimethylphenylamino)]methylnaphtalene (2), and finally, the compound (3) was obtained by N-alkylation reaction of (2) with methyl iodine (CH3I) and potassium carbonate (K2CO3) in acetone. Final compound (3) was purified by chromatographic column. The XRPD pattern for the new compound, 1-[N-(methyl)-(3,5-dimethylphenylamino)]methylnaphthalene, was obtained. This compound crystallizes in monoclinic system with space group P21/a (No. 14) and refined unit-cell parameters a=13.260(4) Å, b=15.495(5) Å, c=7.719(5) Å, β=90.19(6), and V=1586(1) Å3. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|