[Mo3ReS4(O)2(S2P(OEt)2)5]: an example of chalcogenide cluster with a highly oxidized Mo3ReS49+ core

Autor:	Cristian Vicent, Rosa Llusar, Maxim N. Sokolov
Rok vydání:	2005
Předmět:	Stereochemistry Chalcogenide General Chemical Engineering chemistry.chemical_element General Chemistry Crystal structure Rhenium Medicinal chemistry chemistry.chemical_compound chemistry Acetone Cluster (physics) Molecule Hydrothermal synthesis Methanol
Zdroj:	Comptes Rendus Chimie. 8:1815-1819
ISSN:	1631-0748
Popis:	Hydrothermal reaction of [Mo3S4(H2O)9]4+ with [Re(CO)5Br] at 140 °C in 4 M HCl gives a brown product, which upon treatment with KS2P(OEt)2 and recrystallyzation from an acetone/methanol mixture gives the title product via unstable [Mo3ReS4((EtO)2PS2)6]. The crystal structure of [Mo3ReS4(O)2(S2P(OEt)2)5] was determined. To cite this article: R. Llusar et al., C. R. Chimie 8 (2005).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::945882285087c1448504c7012f5c106d https://doi.org/10.1016/j.crci.2005.03.015 Zobrazit plný text záznamu