[Mo3ReS4(O)2(S2P(OEt)2)5]: an example of chalcogenide cluster with a highly oxidized Mo3ReS49+ core
Autor: | Cristian Vicent, Rosa Llusar, Maxim N. Sokolov |
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Rok vydání: | 2005 |
Předmět: | |
Zdroj: | Comptes Rendus Chimie. 8:1815-1819 |
ISSN: | 1631-0748 |
Popis: | Hydrothermal reaction of [Mo3S4(H2O)9]4+ with [Re(CO)5Br] at 140 °C in 4 M HCl gives a brown product, which upon treatment with KS2P(OEt)2 and recrystallyzation from an acetone/methanol mixture gives the title product via unstable [Mo3ReS4((EtO)2PS2)6]. The crystal structure of [Mo3ReS4(O)2(S2P(OEt)2)5] was determined. To cite this article: R. Llusar et al., C. R. Chimie 8 (2005). |
Databáze: | OpenAIRE |
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