Synthesis of novel 1,2,3-triazole based polycarboxylic acid functionalised ligands for MOF systems
| Autor: | D. Bradley G. Williams, Louis-Charl Cloete Coetzee, Alfred Muller, Yonas H. Belay |
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| Rok vydání: | 2019 |
| Předmět: |
1
2 3-Triazole Solid structure 010405 organic chemistry Ligand Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Combinatorial chemistry Copper 0104 chemical sciences chemistry.chemical_compound chemistry Drug Discovery Click chemistry Metal-organic framework |
| Zdroj: | Tetrahedron Letters. 60:501-503 |
| ISSN: | 0040-4039 |
| Popis: | Copper catalysed click reactions are excellent tools to generate various 1,2,3-triazole linked polytopic aromatic carboxylates. The general reaction route involves protection of the carboxylates before proceeding with the click reaction. These polycarboxylate azoles are conveniently prepared for potential utility as novel key building blocks for metal organic frameworks. In one case, the ligand crystallises into a solid structure containing 1D, 2D and 3D features, based on a zigzag 1D structure, a ‘chicken mesh’-like 2D structure and a 3D structure with very well-defined channels. |
| Databáze: | OpenAIRE |
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