A pentanuclear {Co5} cluster motif forming a capped breathing kagomé lattice
| Autor: | Shaowu Du, Zhangzhen He, Meiyan Cui |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Metals and Alloys Lattice (group) General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Trigonal bipyramidal molecular geometry Crystallography Paramagnetism Oblate spheroid Materials Chemistry Ceramics and Composites Cluster (physics) Spin moment Magnetization plateau |
| Zdroj: | Chemical Communications. 57:6616-6619 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d1cc01987b |
| Popis: | A new pentanuclear {Co5} cluster motif is found to have a D3h oblate trigonal bipyramidal geometry, which is extended into a 3D triangle network, forming a unique capped breathing kagome lattice. Magnetic results confirmed a paramagnetism down to 2 K, accompanying the disappearance of two-thirds of the spin moment at low-temperature and the appearance of a 1/5 magnetization plateau. |
| Databáze: | OpenAIRE |
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