Rate enhancement via micelle encapsulation for room temperature metal catalyzed Ce(IV) oxidation of p-chlorobenzaldehyde to p-chlorobenzoic acid in aqueous medium at atmospheric pressure
| Autor: | Susanta Malik, Kakali Mukherjee, Sumanta K. Ghosh, Subhendu Sekhar Bhattacharyya, Rumpa Saha, Pintu Sar, Bidyut Saha, Aniruddha Ghosh |
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| Rok vydání: | 2014 |
| Předmět: |
Chemistry
Metal ions in aqueous solution Inorganic chemistry technology industry and agriculture macromolecular substances Condensed Matter Physics Chloride Redox Micelle Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Catalysis Metal Catalytic oxidation Ionic strength visual_art Materials Chemistry medicine visual_art.visual_art_medium Physical and Theoretical Chemistry Spectroscopy medicine.drug |
| Zdroj: | Journal of Molecular Liquids. 190:81-93 |
| ISSN: | 0167-7322 |
| Popis: | The kinetics and mechanism of the Ru(III) and Ir(III) catalyzed oxidation reaction of p-chlorobenzaldehyde by ceric(IV) have been studied spectrophotometrically at constant ionic strength of 2.0 mol dm− 3 in the presence and absence of the cationic surfactant N-cetylpyridinium chloride (CPC) at 30 °C. The oxidized product p-chlorobenzoic acid was confirmed by the 1H NMR, HR Mass and FTIR spectral analysis. Dramatic rate enhancements have been observed in the oxidation of p-chlorobenzaldehyde by ceric(IV) in the presence of metal ions Ru(III) and Ir(III). The rate of oxidation in the presence of catalyst Ru(III) is much faster than in the Ir(III) catalyzed reaction in micellar media. The observed micellar effect is explained on the basis of reverse CPC micelle formation. This phenomenon was identified with the help of UV Spectra and Scanning Electron Microscopy (SEM) images. The presence of CPC micelles at a certain concentration may increase the effective concentration of the reactant in the hydrophobic part and resulting enhancement of the rate. The substrate undergoes effective collision with the expected positive reactive species Ce(SO4)2 + resulting enhancement of the rate. The enhanced local concentration of reactants in the interfacial region of CPC reverse micelle increases the observed rate. The Ru(III) catalyzed oxidation rate has been found to increase up to 5000 fold in micellar media compared to aqueous media. Ru(III) in combination with CPC is the most effective and suitable catalyst for the catalytic oxidation of p-chlorobenzaldehyde to p-chlorobenzoic acid. |
| Databáze: | OpenAIRE |
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