Synthesis and homogeneity range of Yb8−xYxV2O17 in the Yb8V2O17–Y8V2O17 system
| Autor: | Elzbieta Filipek, Mateusz Piz |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Ir absorption
Chemistry Band gap Cell volume Analytical chemistry 02 engineering and technology Crystal structure 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 010406 physical chemistry 0104 chemical sciences Ion Homogeneity (physics) Thermal stability Physical and Theoretical Chemistry 0210 nano-technology Solid solution |
| Zdroj: | Journal of Thermal Analysis and Calorimetry. 130:277-283 |
| ISSN: | 1588-2926 1388-6150 |
| DOI: | 10.1007/s10973-017-6379-0 |
| Popis: | New substitutional limited solid solution of the formula Yb8−xYxV2O17 and 0 < x < 4.0 was synthesised by the solid-state reaction from the mixtures of the compounds Yb8V2O17 and Y8V2O17. The monophasic samples containing Yb8−xYxV2O17 were characterised by powder XRD, DTA, IR, UV–Vis–DRS and SEM methods. The influence of the degree of Y3+ ion incorporation in the crystal lattice of Yb8V2O17 replacing Yb3+ ions, on the thermal stability, unit cell volume, band gap energies as well as on the position of the IR absorption bands in the spectrum of Yb8−xYxV2O17 was determined. The morphology of Yb8V2O17 and solid solution was analysed. |
| Databáze: | OpenAIRE |
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