Cationic metal nitrosyl complexes. IV. Polymerization of olefins with dinitrosyl iron complexes

Autor:	A. Revillon, C. Billard, D. Ballivet-Tkatchenko
Rok vydání:	1981
Předmět:	chemistry.chemical_compound Monomer Polymerization chemistry Polymer chemistry Cationic polymerization Living polymerization Chain transfer Photochemistry Ionic polymerization Tetrahydrofuran Styrene
Zdroj:	Journal of Polymer Science: Polymer Chemistry Edition. 19:1697-1706
ISSN:	1542-9369 0360-6376
DOI:	10.1002/pol.1981.170190710
Popis:	The polymerization of styrene was performed with new cationic iron complexes, (Fe(N-O)2Sn)+PF6−(BF4−, CIO4−), where Sn represents solvent molecules such as CH2Cl2, THF, and MeCN. Kinetic experiments showed a first-order dependence of (Rp)0 on the monomer and iron complex concentrations. The molecular weight determinations suggested that the termination process is fast and occurs by chain transfer to monomer. An extension of this polymerization to α-methylstyrene, isobutene, tetrahydrofuran, and styrene-methylmethacrylmate system emphasized the cationic nature of the reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::941b5d8f3ea712f6041d8da70abd5607 https://doi.org/10.1002/pol.1981.170190710 Zobrazit plný text záznamu Plný text