Anomalies dans L'esterification D'acides Éthyléniques par la Méthode AU N,N′-Carbonyldiimidazole

Autor: Evelyne Montaudon, Monique Campagnole, M. J. Bourgeois, Bernard Maillard
Rok vydání: 2010
Předmět:
Zdroj: Bulletin des Sociétés Chimiques Belges. 91:725-728
ISSN: 0037-9646
Popis: The reaction of N,N′-carbonyldiimidazole with but-3 enoic acid did not lead to the expected azolide; its rearrangement into conjugated isomer was followed by imidazole addition to the double bond. These two reactions make inefficient this preparative method for esters and peresters of alkyl substituted α, β-ethylenic acids and β,γ-ethylenic acids without substituent on the α-carbon.
Databáze: OpenAIRE