Anomalies dans L'esterification D'acides Éthyléniques par la Méthode AU N,N′-Carbonyldiimidazole
Autor: | Evelyne Montaudon, Monique Campagnole, M. J. Bourgeois, Bernard Maillard |
---|---|
Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Bulletin des Sociétés Chimiques Belges. 91:725-728 |
ISSN: | 0037-9646 |
Popis: | The reaction of N,N′-carbonyldiimidazole with but-3 enoic acid did not lead to the expected azolide; its rearrangement into conjugated isomer was followed by imidazole addition to the double bond. These two reactions make inefficient this preparative method for esters and peresters of alkyl substituted α, β-ethylenic acids and β,γ-ethylenic acids without substituent on the α-carbon. |
Databáze: | OpenAIRE |
Externí odkaz: |