A 1,5-cis-guaianolide glucoside from flowers of Arnica mollis
| Autor: | Günter Willuhn, Detlef Wendisch, Daniel Gondol, Irmgard Merfort |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Lignan biology Chemistry Stereochemistry Plant Science General Medicine Nuclear magnetic resonance spectroscopy Horticulture Carbon-13 NMR Sesquiterpene lactone Sesquiterpene biology.organism_classification Biochemistry chemistry.chemical_compound Glucoside Arnica mollis Molecular Biology Lactone |
| Zdroj: | Phytochemistry. 42:1093-1095 |
| ISSN: | 0031-9422 |
| Popis: | The novel sesquiterpene lactone glucoside 2α-O-β- d - glucopyranosyl -4α- hydroxy -1α,5α,11α- H-guai-10(14)-en -12,8α- olide (=2α- hydroxy -11α,13- dihydro-1-epi-inuviscolide -2α-O-β- d - glucopyranoside ) was isolated from flowerheads of Arnica mollis . Its structural elucidation was carried out by NMR spectroscopy ( 1 H and 13 C NMR, 1 H 1 H COSY, HMBC, HMQC and 1 H 1 H NOESY) and mass spectrometry (DCI). Additionally, the lignan (+)-pinoresinol-4′-β- d -glucopyranoside and benzyl-β-glucoside were isolated and identified. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect