Synthesis and Crystal Structure of New Heterocyclic Compounds Containing 1,2,3-Triazole Moiety

Autor: Zhi-Qiang Dong, Fang-Ming Liu, Yong-Ming Zeng
Rok vydání: 2011
Předmět:
Zdroj: Journal of Chemical Crystallography. 41:1158-1164
ISSN: 1572-8854
1074-1542
Popis: A series of new heterocyclic compounds bearing 1,2,3-triazole moiety were synthesized using 4-acetyl-2-phenyl-1,2,3-triazole 1 as the starting material. The target compounds were prepared and the structures were characterized by IR, 1H NMR, MS and elemental analysis. Meanwhile, the crystal structures of the synthesized compounds were also furthered confirmed by X-ray diffraction analysis. Compound 3b crystallized in the monoclinic P2(1)/c space group with unit cell parameters a = 10.6974(17) A, b = 20.356(3) A, c = 7.8049(12) A, α = 90°, β = 102.840(3)°, γ = 90o, V = 1657.1(5) A3, Z = 4, T = 293(2) K. Compound 7c crystallized in the Triclinic P-1 space group with unit cell parameters a = 7.364(2) A, b = 7.366(2) A, c = 26.089(8)A, α = 87.114(7)°, β = 87.040(7) (3)°, γ = 82.337(7)°, V = 1399.2(7) A3, Z = 2, T = 293(2) K. Compound 10c crystallized in the Triclinic P-1 space group with unit cell parameters a = 9.8152(10) A, b = 10.0806(13) A, c = 11.1267(14) A, α = 100.344(3)°, β = 111.975(3)°, γ = 107.852(3)°, V = 916.18(19) A3, Z = 2, T = 293(2) K. New heterocyclic compounds bearing 1,2,3-triazole moiety were synthesized, which may have potential biological and medical applications.
Databáze: OpenAIRE
Externí odkaz: