Highly Reactive Calcium for the Preparation of Organocalcium Reagents: 1-Adamantyl Calcium Halides and their Addition to Ketones: 1-(1-Adamantyl)Cyclohexanol

Autor: Reuben D. Rieke, Tse-Chong Wu, Loretta I. Rieke
Rok vydání: 2003
Předmět:
Zdroj: Organic Syntheses
DOI: 10.1002/0471264180.os072.18
Popis: Highly reactive calcium for the preparation of organocalcium reagents: 1-adamantyl calcium halides and their addition to ketones: 1-(1-adamantyl)cyclohexanol product: 1-(1-adamantyl)cyclohexanol unknown: 1-octylcyclohexanol unknown: 1-(1-adamantyl)cyclohexanol Keywords: addition, to CO; Grignard and related reactions; metalation reactions, calcium; metalation reactions, calcium; reduction, miscellaneous; tetrahydrofuran
Databáze: OpenAIRE