Effect of diazoalkane structure on the stereoselectivity of rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed cyclopropanations

Autor:	Huw M. L. Davies, Paul R. Bruzinski, Michael J. Fall
Rok vydání:	1996
Předmět:	chemistry.chemical_compound chemistry Organic Chemistry Drug Discovery Enantioselective synthesis Phenyl group chemistry.chemical_element Stereoselectivity Biochemistry Medicinal chemistry Decomposition Catalysis Rhodium
Zdroj:	Tetrahedron Letters. 37:4133-4136
ISSN:	0040-4039
Popis:	Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed decomposition of diazoalkanes containing a methyl ester and either a vinyl or a phenyl group in the presence of alkenes results in highly diastereoselective and enantioselective cyclopropanations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::938e8b4240d9376053ec581604e39074 https://doi.org/10.1016/0040-4039(96)00823-4 Zobrazit plný text záznamu Full Text from ScienceDirect