Effect of dissolved small molecules on the mechanical relaxation behavior of polycarbonate
| Autor: | H. G. Brion, I. Böhm, Reiner Kirchheim |
|---|---|
| Rok vydání: | 2000 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Organic Chemistry Analytical chemistry chemistry.chemical_element Sorption 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Matrix (chemical analysis) chemistry visual_art Materials Chemistry visual_art.visual_art_medium Relaxation (physics) Molecule Polycarbonate 0210 nano-technology Carbon Intensity (heat transfer) |
| Zdroj: | Polymer. 41:6613-6617 |
| ISSN: | 0032-3861 |
| DOI: | 10.1016/s0032-3861(99)00888-5 |
| Popis: | After sorption of gas molecules (CO 2 , C 2 H 4 ) in polycarbonate, a new damping peak appears and the intrinsic γ-relaxation is depressed. The new peak increases in intensity and shifts to lower temperature with increasing gas concentration. This relaxation could be attributed to jumps of the gas molecules inside the polymer matrix similar to the Snoek relaxation of carbon in α-iron. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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