Internal Reforming of Methane at Ni/YSZ and Ni/CGO SOFC Cermet Anodes
| Autor: | D. Fouquet, H. Timmermann, Ellen Ivers-Tiffée, Rainer Reimert, André Weber, U. Hennings |
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| Rok vydání: | 2006 |
| Předmět: |
Materials science
Methane reformer Renewable Energy Sustainability and the Environment Energy Engineering and Power Technology chemistry.chemical_element Cermet Methane Anode chemistry.chemical_compound chemistry Chemical engineering Gas composition Gas chromatography Carbon Yttria-stabilized zirconia |
| Zdroj: | Fuel Cells. 6:307-313 |
| ISSN: | 1615-6854 1615-6846 |
| DOI: | 10.1002/fuce.200600002 |
| Popis: | The internal reforming of methane on Ni/CGO and Ni/YSZ anodes was investigated with single cells operated at steam to carbon ratios from 0 to 3 and at temperatures of 800 °C and 950 °C. The incorporation of gas extraction ports allowed the measurement of the local gas composition in the anode gas compartment by gas chromatography. The methane conversion is presented as a function of feed gas composition, temperature, gas flow velocity, and electrical load. The impact of the anode material on the reforming reaction and on cell performance is shown. Methane conversion along the Ni/CGO anode was calculated with a one-dimensional model; the required kinetic parameters were obtained by data fitting. |
| Databáze: | OpenAIRE |
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