XPS studies of superconducting Mo–Ru–Rh–Pd alloy

Autor:	Yong Joon Park, Hyung Yeol Pyo, Jong-Gyu Lee, Jong Goo Kim, Yong-Seog Jeon, Kwang Yong Jee, Won Ho Kim
Rok vydání:	2000
Předmět:	Insoluble residue Superconductivity Chemistry Mechanical Engineering Alloy Metallurgy Binding energy Metals and Alloys engineering.material Arc melting Electronegativity X-ray photoelectron spectroscopy Mechanics of Materials Materials Chemistry engineering Physical chemistry Core level
Zdroj:	Journal of Alloys and Compounds. 298:291-294
ISSN:	0925-8388
DOI:	10.1016/s0925-8388(99)00664-7
Popis:	Superconducting quaternary alloys, Mo25Ru50Rh12.5Pd12.5, Mo30Ru45Rh12.5Pd12.5, Mo40Ru40Rh10Pd10 and Mo50Ru20Rh15Pd15 have been prepared using an arc melting furnace. X-ray photoelectron spectroscopic (XPS) measurements indicate that the binding energies of Pd 3d3/2 and 3d5/2 peaks increased by 0.5–0.9 eV. XPS measurements for several binary alloys, Pd1−xMox, Pd1−xRux, Pd1−xRhx and Pd1−xAgx (x=0.25, 0.5, 0.75 and 1.0) were also carried out to study the origin of the binding energy shifts of Pd 3d3/2 and 3d5/2 peaks. The binding energy shifts are found to be irrespective of the electronegativity of the constituent elements in the quaternary alloys, but rather closely related to the final state effects.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::934b9dc0c48f54f14fdc5cc8e0b84e0d https://doi.org/10.1016/s0925-8388(99)00664-7 Zobrazit plný text záznamu Full Text from ScienceDirect