Dehydration of Bioethanol by Hybrid Process Liquid–Liquid Extraction/Extractive Distillation

Autor: Adriana Avilés Martínez, Agustín Jaime Castro-Montoya, Salvador Hernández, Juan Gabriel Segovia-Hernández, Jaime Saucedo-Luna, Fernando Israel Gómez-Castro
Rok vydání: 2011
Předmět:
Zdroj: Industrial & Engineering Chemistry Research. 51:5847-5855
ISSN: 1520-5045
0888-5885
DOI: 10.1021/ie200932g
Popis: Bioethanol is among the most promising of biofuels because it has an energy content similar to gasoline while generating lower pollutant emissions than gasoline. But, in order to be used as an automotive fuel mixed with gasoline, ethanol must have less than 0.5 wt % of water. To achieve required ethanol purity, in light of the fact that the ethanol–water mixture forms an azeotrope, unconventional separation techniques such as extractive distillation or azeotropic distillation are necessary. However, the purification of ethanol using conventional distillation followed by extractive distillation has the disadvantage of high cost of services. Thus, this study proposes alternative hybrid systems using liquid–liquid extraction and extractive distillation. The use of n-dodecane as entrainer for liquid–liquid extraction and glycerol as entrainer for extractive distillation has been considered. The proposed systems are analyzed and a comparison is done on their performance in terms of energy and total annual cost...
Databáze: OpenAIRE