A Facile Reduction of Copper(II) Leading to Formation of Stable Copper(I) Complexes. Redox Properties of Four- and Five-coordinate Copper Complexes

Autor:	Akitsugu Nakahara, Masazo Kimura, Takeshi Sakurai
Rok vydání:	1981
Předmět:	Reduction (complexity) chemistry.chemical_compound chemistry Inorganic chemistry Chlorate Disulfide bond chemistry.chemical_element Cuprate General Chemistry Copper Redox
Zdroj:	Bulletin of the Chemical Society of Japan. 54:2976-2978
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.54.2976
Popis:	Schiff bases derived from 2-pyridinecarbaldehyde and 1,6-hexanediamine or bis(2-aminoethyl) disulfide gave stable Cu(I) complexes instead of Cu(II) complexes by reactions with copper(II) per chlorate. The facile reduction of copper(II) has been discussed on the basis of systematic comparisons of redox and ESR properties of about 20 complexes of similar structures.
Databáze:	OpenAIRE
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