Observation of a stable hemiortho ester anion. Acidity constant for a tetrahedral intermediate
| Autor: | Robert A. McClelland, N. Esther Seaman, David A. Cramm |
|---|---|
| Rok vydání: | 1984 |
| Předmět: |
biology
Chemistry General Chemistry Reaction intermediate Biochemistry Medicinal chemistry Catalysis Acid dissociation constant Ion Hydrolysis Colloid and Surface Chemistry Reaction rate constant Tetrahedral carbonyl addition compound biology.protein Organic chemistry Equilibrium constant Organic anion |
| Zdroj: | Journal of the American Chemical Society. 106:4511-4515 |
| ISSN: | 1520-5126 0002-7863 |
| Popis: | Le p-nitrobenzoate de pinacol subit une cyclisation rapide et reversible dans une base, conduisant a un intermediaire anionique tetraedrique, la base conjuguee du nitro-4' phenyl-2 tetramethyl-4,4,5,5 dioxolanne-1,3ol-2. Caracterisation de l'anion. Constantes de vitesse et d'equilibre |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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