Versatile Interpenetrating Polymer Network Approach to Robust Stretchable Electronic Devices

Autor: Ping-Hsun Chu, Michael McBride, Bailey Risteen, Guoyan Zhang, Tim J. Dunn, Savannah Lee, Yo-Han Kwon, Nils Persson, Michael F. Toney, Elsa Reichmanis, Zhibo Yuan
Rok vydání: 2017
Předmět:
Zdroj: Chemistry of Materials. 29:7645-7652
ISSN: 1520-5002
0897-4756
DOI: 10.1021/acs.chemmater.7b03019
Popis: The pursuit of intelligent optoelectronics could have profound implications on our future daily life. Simultaneous enhancement of the electrical performance, mechanical stretchability, and optical transparency of semiconducting polymers may significantly broaden the spectrum of realizable applications for these materials in future intelligent optoelectronics, i.e., wearable devices, electronic skin, stretchable displays, and a vast array of biomedical sensors. Here, semiconducting films with significantly improved mechanical elasticity and optical transparency, without affecting the film’s electronic conductivity even under 100% strain, were prepared by blending only a small amount (below 1 wt %) of either p-type or n-type commercial semiconductor polymers. We demonstrate that a self-organized versatile conjugated polymer film displaying an interpenetrating polymer network is formed in the semiconducting films and is crucial for the observed enhancement of elasticity, optical transparency, and charge-carr...
Databáze: OpenAIRE