Enhancement of Raman scattering from single-walled carbon nanotubes on densely-arranged two-dimensional gold nanoparticle assemblies

Autor: Koji Uchida, Joe Otsuki, Kosuke Sugawa, Shuto Igari, Wataru Inoue
Rok vydání: 2017
Předmět:
Zdroj: Molecular Crystals and Liquid Crystals. 654:151-156
ISSN: 1563-5287
1542-1406
DOI: 10.1080/15421406.2017.1358022
Popis: We investigated surface-enhanced Raman scattering properties of single-stranded DNA-functionalized single-walled carbon nanotubes (ssDNA-SWCNTs) modified on densely-arranged two-dimensional Au nanoparticle assemblies. The ssDNA-SWCNTs was prepared by sonicating a mixture solution of the ssDNA and high-pressure carbon monoxide (Hipco) SWNTs. The Au nanoparticle assemblies were prepared by an organic solvent-mediated liquid-liquid interface assembly technique. The assemblies showed a strong longitudinal dipole coupling mode, which lead to the generation of hot spots at a near infrared region. The Raman signals characteristic of the SWCNTs were significantly enhanced (average enhancement factor: 199) by the coupling mode.
Databáze: OpenAIRE