Synthesis of 2-phenyl-1,3-di(4-pyridyl)naphthvalene by photoinduced reversible valence isomerization of 2-phenyl-1,3-di(4-pyridyl)naphthalene

Autor:	Feng Li, Junpeng Zhuang, Haijun Hao, Shouliang Zhang, Dongyue Chen
Rok vydání:	2019
Předmět:	chemistry.chemical_compound Valence (chemistry) chemistry 010405 organic chemistry Organic Chemistry Drug Discovery 010402 general chemistry 01 natural sciences Biochemistry Isomerization Medicinal chemistry 0104 chemical sciences Naphthalene
Zdroj:	Tetrahedron Letters. 60:1416-1420
ISSN:	0040-4039
Popis:	2-Phenyl-1,3-di(4-pyridyl)naphthvalene 3a was synthesized by the photoinduced reversible valence isomerization of 2-phenyl-1,3-di(4-pyridyl)naphthalene 2a. Then, 3a was converted into 3-phenyl-1,2-di(4-pyridyl)naphthalene 4a and 2a simultaneously. The t1/2 of 3a in DMSO-d6 at 90 °C was 2 h, while that at 110 °C was approximately 10 min.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9313ae0c4535228905a8d40d5728fa00 https://doi.org/10.1016/j.tetlet.2019.04.036 Zobrazit plný text záznamu Full Text from ScienceDirect