A pseudo-octahedral tungsten oxo compound, [WO(C18H12O)(C13H13P)3].C7H8

Autor:	Phillip E. Fanwick, Judith L. Kerschner, C. E. Kriley, I. P. Rothwell
Rok vydání:	1994
Předmět:	Tris Ligand Stereochemistry chemistry.chemical_element General Medicine Crystal structure Tungsten Toluene General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound Crystallography chemistry Octahedron Molecule
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 50:1193-1196
ISSN:	0108-2701
Popis:	The compound tris(diphenylmethylphosphine)oxo-[1,1':3',1″-terphenyl-2'-olato(2-)-C 2 O]tungsten(IV) toluene solvate contains one cyclometallated 2',6-diphenylphenoxide ligand. A pseudo-octahedral geometry exists for the WO 2 CP 3 core with the terminal oxo and aryloxide O atoms mutually trans. W-O(terminal oxo group)=1.717 (3), W-O(aryloxide)=2.059 (3), W-C=2.151 (5), W-P=2.550 A (average)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::92feba70583ddc5d0c9a928858206974 https://doi.org/10.1107/s0108270194000272 Zobrazit plný text záznamu Plný text