Synthesis, growth and characterization of nitramino sulphonic acid (NASA) NLO single crystals
| Autor: | Martina Mejeba Xavier Methodius, Bhagavannarayana Godavarti, Vijayan Narayanasamy, Prem Anand Devarajan, Anbarasu Selvaraj, Samson Yesuvadian |
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| Rok vydání: | 2015 |
| Předmět: |
Aqueous solution
Materials science business.industry Band gap Second-harmonic generation Dielectric Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Crystal Optics Physical chemistry Molecule Electrical and Electronic Engineering Fourier transform infrared spectroscopy business Single crystal |
| Zdroj: | Optik. 126:95-100 |
| ISSN: | 0030-4026 |
| DOI: | 10.1016/j.ijleo.2014.08.138 |
| Popis: | New laser NLO (nonlinear optical) inorganic material nitramino sulphonic acid (NASA) [H2N2SO5] was synthesized and confirmed by NMR and XRD spectral analysis. NASA crystal was grown from aqueous solution by slow solvent evaporation technique at room temperature. Single crystal XRD revealed that NASA crystallizes in noncentrosymmetric space group Pba2. The structural purity was confirmed by powder XRD. The crystalline perfection of the grown crystal was analyzed by High resolution XRD. The optical transmittance and band gap energies of the crystal were studied by UV–vis–NIR spectral analysis. Polarizability factors attributing to dielectric properties were analyzed by dielectric studies. Second harmonic generation efficiency was also studied by Kurtz–Perry powder technique. Explosive sensitive destable nitramino bond was converted to optically energetic by stabilizing N NO2 bond within sulphonic acid host molecules. |
| Databáze: | OpenAIRE |
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