A Mild and Versatile Method for the Synthesis of Alkyl Ethers from Methoxymethyl Ethers and Application to the Preparation of Sterically Crowded Ethers

Autor:	Hiromichi Fujioka, Yutaka Minamitsuji, Atsuhisa Kawaguchi, Tomohiro Maegawa, Ozora Kubo, Yoshifumi Ueyama
Rok vydání:	2012
Předmět:	Steric effects chemistry.chemical_classification chemistry.chemical_compound chemistry Organic Chemistry Nucleophilic substitution Organic chemistry Salt (chemistry) Ether Alkylation Catalysis Alkyl
Zdroj:	Advanced Synthesis & Catalysis. 354:1861-1866
ISSN:	1615-4150
Popis:	A mild and divergent route for the synthesis of alkyl ethers from methoxymethyl (MOM) and methoxyethyl (ME) ether derivatives via pyridinium-type salt intermediates has been developed. The addition of organocuprates to the salts afforded the corresponding alkyl ethers, including highly crowded ones, in high yields even in the presence of acid- or base-sensitive functional groups.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::92df28435202d8085d7af71d124f59fd https://doi.org/10.1002/adsc.201200290 Zobrazit plný text záznamu Plný text ve formátu PDF