Evaluation of bonded layer disorder from thermodynamic behavior of methylaminopropyl groups immobilized on sio2

Autor: Viktoria D. Oleynik, V. L. Budarin, Vladimir Zaitsev
Rok vydání: 1998
Předmět:
Zdroj: Macromolecular Symposia. 136:99-102
ISSN: 1022-1360
Popis: Thermodynamic characteristics of reaction between proton and methylaminopropyl groups that are covalently bonded to silica gel surface were calculated. First evidence of short-distance interaction between neighboring bonded amines was obtained. Addition of the first proton does not destroy such interaction. Second proton promotes significant geometry changing.
Databáze: OpenAIRE