Some chemical transformations of 5-(propyn-2-yl)bicyclo[2.2.1]-2-heptene

Autor:	M. G. Veliev, L. A. Yanovskaya, R. F. Gakhramanov, M. M. Guseinov
Rok vydání:	1982
Předmět:	chemistry.chemical_compound Chemical transformation Bicyclic molecule Trimethylsilyl chemistry Acrolein Side chain Organic chemistry General Chemistry Grignard reagent Mannich reaction Heptene Medicinal chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 31:2282-2285
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00958411
Popis:	The Grignard reagent, obtained from 5-(propyn-2-yl)bicyclo[2.2.1]-2-heptene, reacts easily with Ac2O, Et2SiCl2, Me3SiCl, and acrolein to give in high yields [2.2.1]bicyclo-2-heptene derivativesthat contain in the side chain either an acetyl, diethylsilyl, trimethylsilyl, or a hydroxypropen-1-yl group. The Mannich reaction was also run with 5-(propyn-2-yl)bicyclo[2.2.1]-2-heptene.
Databáze:	OpenAIRE
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