Robust high-connected rare-earth MOFs as efficient heterogeneous catalysts for CO2conversion
| Autor: | Yu-Yang Zhang, Na Wei, Xue-Jun Gu, Rong-Xia Zuo, Zheng-Bo Han |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Chemistry
Rare earth Metals and Alloys Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Combinatorial chemistry Catalysis Cycloaddition 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Materials Chemistry Ceramics and Composites SBus 0210 nano-technology Topology (chemistry) |
| Zdroj: | Chemical Communications. 53:3224-3227 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c7cc00363c |
| Popis: | Two series of chemically and thermally stable rare-earth MOFs were constructed using trinuclear [M3(μ3-OH)(COO)6] SBUs and linear dicarboxylate linkers, which feature three-dimensional 12-connected frameworks with an hcp topology. These materials contain a large density of Lewis acidic sites, leading to high catalytic activity towards the cycloaddition of CO2 and epoxides under mild conditions. |
| Databáze: | OpenAIRE |
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