Ionic CNT-supported Ru–carbene complex for recyclable ring-closing metathesis
Autor: | Sujin Lee, Sang‐gi Lee, Ju Yeon Shin |
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Rok vydání: | 2013 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 54:684-687 |
ISSN: | 0040-4039 |
DOI: | 10.1016/j.tetlet.2012.12.002 |
Popis: | The ionic multi-walled carbon nanotubes (IM-f-MWCNTs), which were covalently functionalized with imidazolium salt, have been utilized as support materials for the immobilization of Hoveyda-type Ru–carbene complex. The catalytic activity and recyclability of the ionic CNT-supported Ru–carbene complexes have been investigated for ring-closing metathesis of various dienes, and the recovered catalyst can be reused up to 10 times without any significant loss of catalytic activity. |
Databáze: | OpenAIRE |
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