β-cyclodextrin as a selective agent for the separation of o-,m- and p-xylene and ethylbenzene mixtures in gas-liquid chromatography

Autor: Danuta Sybliska, Tomasz Kościelski
Rok vydání: 1983
Předmět:
Zdroj: Journal of Chromatography A. 261:357-362
ISSN: 0021-9673
DOI: 10.1016/s0021-9673(01)87963-2
Popis: The dependence of the elution patterns of o , m - and p-xylenes and ethylbenzene on the β-cyclodextrin concentration in the formamide stationary phase deposited on Celite has been studied in the temperature range 50–70°C. It has been found that stereoselective molecular inclusion processes take place in the formamide medium, thus, modifying its chromatographic properties. Such systems result in a gain in stereoselectivity while at the same time retaining all the advantages of partition gas chromatography. The conditions for complete separation of the investigated compounds have been elaborated.
Databáze: OpenAIRE