Growth and characterization of PbSe and Pb1−xSnxSe on Si (100)

Autor: Patrick J. McCann, X. M. Fang, H. K. Sachar, I. Chao
Rok vydání: 1999
Předmět:
Zdroj: Journal of Applied Physics. 85:7398-7403
ISSN: 1089-7550
0021-8979
Popis: PbSe and Pb1−xSnxSe layers, with thicknesses ranging from 1 to 5 μm, were grown by liquid phase epitaxy on Si (100) substrates using PbSe/BaF2/CaF2 buffer layers grown by molecular beam epitaxy. Optical Nomarski characterization revealed excellent surface morphologies and good growth solution wipeoffs. Although most PbSe layers were free of cracks over the entire 8×8 mm2 substrate area, ternary Pb1−xSnxSe layers exhibited varying crack densities ranging from zero in the center of samples to over 30 cracks/cm at the edges. High resolution x-ray diffraction (HRXRD) measurements of crack-free PbSe layers showed a residual in-plane tensile strain of 0.21% indicating that most of the 0.74% thermal expansion mismatch strain was absorbed by plastic deformation. HRXRD full width half maxima values of less than 200 arc sec showed that these layers also had high crystalline quality. Fourier transform infrared transmission measurements at room temperature and 110 K showed absorption edges in the range of 270–80 meV,...
Databáze: OpenAIRE