Characterization of deep defects in boron-doped CVD diamond films using transient photocapacitance method

Autor: Takanori Hori, Taishi Kodama, Osamu Maida, Toshimichi Ito
Rok vydání: 2017
Předmět:
Zdroj: Materials Science in Semiconductor Processing. 70:203-206
ISSN: 1369-8001
DOI: 10.1016/j.mssp.2016.12.001
Popis: We have developed a highly-sensitive transient photocapacitance measurement (TPM) system for deep defects in wide bandgap materials, and applied it to characterize the boron-doped diamond films grown on a high-pressure/high-temperature-synthesized Ib diamond substrate using high-power-density microwave-plasma chemical vapor deposition method. The developed TPM system has both a low detection limit of less than 0.5 fF for changes in the photocapacitance and a low measurement temperature drift of less than 0.03 K in 12 h. By using the TPM system, we have successfully found an acceptor-type defect around 1.2 eV above the valence-band maximum for the B-doped diamond film with a considerably high crystalline quality that had some strong exciton emission peaks in the cathodoluminescence spectra taken at ≈80 K. The photoionization cross section and the defect density estimated for the observed defect were 3.1×10 –15 cm 2 and 2.8×10 16 cm −3 , respectively.
Databáze: OpenAIRE