Application of supported lanthanum catalysts in the hydrogenation of nitriles
| Autor: | Diána Balogh-Weiser, Laurence Pirault-Roy, Krisztina Lévay, Zoltán Hell, László Hegedűs, Kinga Juhász |
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| Rok vydání: | 2021 |
| Předmět: |
010405 organic chemistry
Chemistry chemistry.chemical_element Benzyl cyanide 010402 general chemistry Adiponitrile 01 natural sciences Catalysis 0104 chemical sciences Nickel chemistry.chemical_compound Benzonitrile Lanthanum High activity Organic chemistry Physical and Theoretical Chemistry Selectivity |
| Zdroj: | Reaction Kinetics, Mechanisms and Catalysis. 133:687-698 |
| ISSN: | 1878-5204 1878-5190 |
| DOI: | 10.1007/s11144-021-02028-2 |
| Popis: | Nickel and lanthanum on MgO or MgO–Al2O3catalysts were prepared and characterized. The applicability of the catalysts was studied in the liquid-phase hydrogenation of benzonitrile. A La/MgO catalyst showed surprisingly high activity and selectivity. The scope of the reaction was extended to other nitriles (benzyl cyanide, cinnamonitrile, adiponitrile) over this La/MgO catalyst. |
| Databáze: | OpenAIRE |
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