Facile access to novel 1,2,4-oxadiazinan-5-ones via [3 + 3] cycloaddition of in situ generated azaoxyallyl cations with nitrones

Autor:	Xiu-Qing Song, Hai-Liang Pang, Hong-Wu Zhao, Yu-Di Zhao, Xiao-Qin Chen, Juan Du, Ning-Ning Feng, Li-Jiao Zhao, Yue-Yang Liu
Rok vydání:	2017
Předmět:	In situ Structure analysis 010405 organic chemistry Chemistry General Chemical Engineering Chemical structure Organic chemistry General Chemistry 010402 general chemistry 01 natural sciences Single crystal Cycloaddition 0104 chemical sciences
Zdroj:	RSC Advances. 7:12916-12922
ISSN:	2046-2069
Popis:	In the presence of Na2CO3, azaoxyallyl cations in situ generated from α-halohydroxamates with nitrones readily underwent [3 + 3] cycloaddition, and gave rise to 1,2,4-oxadiazinan-5-one derivatives in 56–99% chemical yields. The chemical structure of the title compounds was unambiguously identified by X-ray single crystal structure analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9257c14e1e5c90e350328a5342556a9a https://doi.org/10.1039/c6ra27440d Zobrazit plný text záznamu