Synthesis and Characterization of Zn-Carboxylate Metal–Organic Frameworks Containing Triazatruxene Ligands

Autor:	Shane G. Telfer, Adil Alkaş
Rok vydání:	2019
Předmět:	010405 organic chemistry Supramolecular chemistry Substituent chemistry.chemical_element General Chemistry Zinc Crystal structure 010402 general chemistry 01 natural sciences Tricarboxylate 0104 chemical sciences Crystallography chemistry.chemical_compound chemistry Zinc nitrate Metal-organic framework Carboxylate
Zdroj:	Australian Journal of Chemistry. 72:786
ISSN:	0004-9425
DOI:	10.1071/ch19213
Popis:	Reactions between triazatruxene-based tricarboxylate ligands, H3tat-R, and zinc nitrate under solvothermal conditions afforded new metal–organic frameworks (MOFs) with the general formula [Zn3(tat-R)2(H2O)2], MUF-tat-R (R=a hydrocarbon substituent on the triazatruxene nitrogen atoms). Single-crystal X-ray diffraction analysis revealed that these frameworks are 3D networks with a (10,3)-a topology. Linear trinuclear zinc clusters are connected to tat ligands to form chiral channels that accommodate the substituents on the tat ligands. MUF-tat and MUF-tat-benzyl crystallize in a cubic crystal system whereas MUF-tat-butyl and MUF-tat-hexyl are tetragonal. MUF-tat-benzyl retains its porosity on activation, which was confirmed by gas adsorption studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::924da1a9b9690ac255d7c449bce24866 https://doi.org/10.1071/ch19213 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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