Intermolecular C–H Activations of Hydrocarbons Initiated by Cp*M(NO)(CH2CMe3)(η3-CH2CHCHPh) Complexes (M = Mo, W)
Autor: | Peter Legzdins, Rhett A. Baillie, Michelle E. Thibault, Catherine Chow, Renee W. Y. Man, Monica V. Shree, W. Stephen McNeil |
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Rok vydání: | 2011 |
Předmět: | |
Zdroj: | Organometallics. 30:6201-6217 |
ISSN: | 1520-6041 0276-7333 |
Popis: | Thermolysis of Cp*W(NO)(CH2CMe3)(η3-CH2CHCHPh) (1) at 55 °C leads to the loss of neopentane and the formation of the 16e η2-allene intermediate complex Cp*W(NO)(η2-CH2═C═CHPh) (A), which has been i... |
Databáze: | OpenAIRE |
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