Intermolecular C–H Activations of Hydrocarbons Initiated by Cp*M(NO)(CH2CMe3)(η3-CH2CHCHPh) Complexes (M = Mo, W)

Autor: Peter Legzdins, Rhett A. Baillie, Michelle E. Thibault, Catherine Chow, Renee W. Y. Man, Monica V. Shree, W. Stephen McNeil
Rok vydání: 2011
Předmět:
Zdroj: Organometallics. 30:6201-6217
ISSN: 1520-6041
0276-7333
Popis: Thermolysis of Cp*W(NO)(CH2CMe3)(η3-CH2CHCHPh) (1) at 55 °C leads to the loss of neopentane and the formation of the 16e η2-allene intermediate complex Cp*W(NO)(η2-CH2═C═CHPh) (A), which has been i...
Databáze: OpenAIRE