Evolution of local electronic and atomic structure of Co-doped LiMn2O4 cathode material for lithium rechargeable batteries
| Autor: | Yin-Wen Tsai, Raman Santhanam, Bing-Joe Hwang, D.G. Liu, Y.W. Wu, J.F. Lee, Shao-Kang Hu |
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| Rok vydání: | 2003 |
| Předmět: |
X-ray absorption spectroscopy
Absorption spectroscopy Renewable Energy Sustainability and the Environment Chemistry Spinel Analytical chemistry Energy Engineering and Power Technology chemistry.chemical_element Electronic structure engineering.material Cathode law.invention Bond length law engineering Lithium Electrical and Electronic Engineering Physical and Theoretical Chemistry Absorption (electromagnetic radiation) |
| Zdroj: | Journal of Power Sources. 123:206-215 |
| ISSN: | 0378-7753 |
| Popis: | In situ X-ray absorption spectroscopy (XAS) techniques are performed to investigate the evolution of the local electronic and atomic structure of a spinel cathode material LiCo0.2Mn1.8O4 in the 4 V range. Changes in the oxidation state, bond distance, and local disorder of Mn and Co absorbers in the Co-doped LiMn2O4 are measured as a function of potentials. The X-ray absorption near edge spectra shows that charging (Li deintercalation) leads to the oxidation of manganese to Mn4+. On the other hand, Co atoms are also oxidized but the edge energy shift is small, which suggests that Co is also electroactive in LiCo0.2Mn1.8O4 in the 4 V range. The change in the Debye–Waller factor of the Co–O shell is smaller than that of Mn–O shell. Furthermore, from Debye–Waller factor and bond distance values, it appears that the Co environment fluctuates markedly during discharging. |
| Databáze: | OpenAIRE |
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