1H and 13C NMR spectra of N-vinylpyrroles
Autor: | Al'bina I. Mikhaleva, G. A. Kalabin, E. G. Chebotareva, A. S. Atavin, Boris A. Trofimov |
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Rok vydání: | 1975 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 11:315-318 |
ISSN: | 1573-8353 0009-3122 |
Popis: | The position of the substituants in 2, 3-dialkyl-1-vinylpyrroles and 7-methyl-1 vinyl-4,5,6,7-tetrahydroindole was established on the basis of the 1H and 13C NMR spectra. It was found that the S-trans conformation of the N-vinyl group is preferred. It is shown that the condensation of ketoximes with acetylene proceeds through the formation of free pyrroles and that vinyl oximes are not intermediates in the condensation. |
Databáze: | OpenAIRE |
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