Photo-mediated synthesis of 1,2-dideoxy-2-phosphinylated carbohydrates from glycals: the reduction of glycosyl radicals to glycosyl anions

Autor: Hai Li, Kai-Cheng Yu, Jia-Kun Su, Wei Ouyang, Nai-Li Fan, Xiang-Guo Hu
Rok vydání: 2022
Předmět:
Zdroj: Green Chemistry. 24:8280-8291
ISSN: 1463-9270
1463-9262
Popis: A metal-free, photo-mediated method for the synthesis of C2-phosphorylated carbohydrates has been developed, whose reaction mechanism consists of the reduction of a glycosyl radical to a glycosyl anion.
Databáze: OpenAIRE