Reactivity of Mo(PMe3)5H2 towards catecholborane: synthesis and structure of Mo(PMe3)4(η2-H2BCat)H

Autor:	Tony Hascall, Gerard Parkin, Brian M. Bridgewater
Rok vydání:	2000
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Stereochemistry Materials Chemistry Reactivity (chemistry) Physical and Theoretical Chemistry Borohydride Medicinal chemistry Catecholborane Derivative (chemistry)
Zdroj:	Polyhedron. 19:1063-1066
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(00)00350-8
Popis:	Mo(PMe 3 ) 5 H 2 reacts with catecholborane (CatBH) to give Mo(PMe 3 ) 4 (η 2 -H 2 BCat)H. Structural characterization by X-ray diffraction suggests that the complex is best represented as a borohydride complex, as opposed to a boryl-hydride derivative Mo(PMe 3 ) 4 (BCat)H 3 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::91f9156bb2df5e5f3423e76993b64817 https://doi.org/10.1016/s0277-5387(00)00350-8 Zobrazit plný text záznamu Full Text from ScienceDirect