Biomass-mediated synthesis of carbon-supported nanostructured metal sulfides for ultra-high performance lithium-ion batteries
| Autor: | Eileen Fong, Yan Lu |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Nanostructure
Materials science Sulfide Inorganic chemistry chemistry.chemical_element 02 engineering and technology engineering.material 010402 general chemistry 01 natural sciences Nanomaterials Metal chemistry.chemical_compound General Materials Science chemistry.chemical_classification Renewable Energy Sustainability and the Environment Ammonium heptamolybdate General Chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences chemistry visual_art visual_art.visual_art_medium engineering Biopolymer 0210 nano-technology Hybrid material Cobalt |
| Zdroj: | Journal of Materials Chemistry A. 4:2738-2745 |
| ISSN: | 2050-7496 2050-7488 |
| DOI: | 10.1039/c5ta09917j |
| Popis: | A bio-inspired, environmentally friendly route to prepare three-dimensional (3D) hybrid nanostructured materials for lithium-ion batteries (LIBs) is presented. Alginate, a naturally occurring biopolymer, was employed as a template to synthesize molybdenum sulfide (MoS2) nanostructures from ammonium heptamolybdate and L-cysteine precursors under physiological conditions. Here we show that MoS2 precursors did not interact specifically with alginate; instead, MoS2 nanocrystallites were precipitated within a porous alginate matrix made up of hollow nanospheres. In contrast, when cobalt (Co2+) was added to crosslinked alginate mixed with ammonium heptamolybdate and L-cysteine precursors, a highly crosslinked hydrogel network was obtained instead. Upon annealing, CoMoS3.13 nanocrystallites were found to be well-dispersed within a 3D porous carbon matrix (CoMoS3.13@ADC, ADC represents alginate derived carbon). The novel CoMoS3.13@ADC hybrid materials were evaluated as anodes in lithium ion batteries, and were found to have exceptional capability performance, excellent cycle stability and rate performance. The lithiation mechanisms of CoMoS3.13@ADC were proposed; the shortened ion transport paths and rapid reaction kinetics were due to the nano-sized CoMoS3.13 crystals and inter-connected 3D porous structure. In summary, we showed that alginate biopolymers could offer a facile route towards the synthesis of novel 3D metal sulfide hybrid nanomaterials for energy storage applications. |
| Databáze: | OpenAIRE |
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