Mass-spectra of dimethylbicyclo64.4.09decane stereoisomers (2,3-; 2,4-; 2,8- and 2,9-dimethylbicyclo64.4.09decanes)

Autor:	E.Kh. Kurashova, P.I. Sanin, I.M. Lukashenko, Ye.S. Brodskii, I.A. Musayev
Rok vydání:	1977
Předmět:	Crystallography chemistry.chemical_compound Chemistry General Engineering Mass spectrum chemistry.chemical_element Decane Hydrogen atom Photochemistry Carbon Relative stability Methyl group Ion
Zdroj:	Petroleum Chemistry U.S.S.R.. 17:77-84
ISSN:	0031-6458
DOI:	10.1016/0031-6458(77)90056-9
Popis:	1. 1. A study was made of mass-spectra of 29 stereisomers of 2,3-, 2,4-, 2,8- and 2,9-dimethylbicyclo[44.4.0]decanes. 2. 2. Peak intensities of M + and (MCH 3 ) + normally decrease with a reduction of the relative stability of stereoisomers, while peak intensities of ions formed during splitting of rings increase. Splitting of bonds at tertiary carbon atoms with a methyl group increases the probability of migration or separation of the hydrogen atom from the ion formed. 3. 3. It is assumed that molecular and some fragmented ions, particularly (MCH 3 ) + , at least partly retain stereoisomer structural features.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::91ef5364baf9d692a28e86b697198db8 https://doi.org/10.1016/0031-6458(77)90056-9 Zobrazit plný text záznamu