Studies in tertiary amine oxides. Part V—carbon-13 nuclear magnetic resonance spectra of someN-aryl tertiary amines, the correspondingN-oxides and the meisenheimer rearrangement products

Autor: Jasim M. A. Al-Rawi, Mohammed A. Al-Iraqi, Abdul K. S. Al-Kazzaz, Abdul-Hussain Khuthier
Rok vydání: 1982
Předmět:
Zdroj: Organic Magnetic Resonance. 18:104-108
ISSN: 1097-458X
0030-4921
DOI: 10.1002/mrc.1270180212
Popis: The carbon-13 NMR spectra of some N-(2- or 4-nitrophenyl) tertiary amines and their corresponding N-oxides have been analysed. These N-oxides undergo thermal rearrangement to O-arylhydroxylamines, for which the 13C NMR spectral assignments were also carried out. The N-oxidation effect on the aromatic and aliphatic fragments is calculated.
Databáze: OpenAIRE